Towards Quantum Mechanical Model of the Atom

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Towards Quantum Mechanical Model of the Atom: Overview

This topic covers concepts, such as, Quantum Mechanical Model of Atom, de-Broglie's Equation: Dual Nature of Matter, Radial Probability Density & Plot of Radial Probability Function etc.

Important Questions on Towards Quantum Mechanical Model of the Atom

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A 0.66 kg ball is moving with a speed of 100 m/s. The associated wavelength will be   ( h=6.6× 10 34 Js ):

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The measurement of the electron position if associated with an uncertainty in momentum which is equal to 1× 10 18 gcm s 1 . The uncertainty in electron velocity is,

(mass of an electron is   9× 10 28 g )

                                                                                                                                                                                                                               

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If uncertainty in position and momentum are equal, then uncertainty in velocity is :

                                                                                                                                                                                                                               

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Given : The mass of electron is  9.11×1031kg, Planck constant is  6.626×1034Js, the uncertainty involved in the measurement of velocity within a distance of   0.1Å is

                                                                                                                                                                                                                               

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Set of isoelectronic species is

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The position of both, an electron and a helium atom is known within 1.0 nm. Further, the momentum of the electron is known with in 5.0×1026kgms1.The minimum uncertainty in the measurement of the momentum of the helium atom is

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The position of both, an electron and a helium atom is known within 1.0 nm. Further the momentum of the electron is known within    5.0× 10 26 kgm s 1 .  The minimum uncertainty in the measurement of the momentum of the helium atom is

                                                                                                                                                                                                                               

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The electron was shown experimentally to have wave properties by

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An electron beam with a de Broglie wavelength of x Å is accelerated till its wavelength is halved. By what factor will kinetic energy change-

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For s-orbital, 4πr2Ψr2 vs r is plotted. Select correct statement (s).

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Note: S = spherical surface at given distance. P = Point (very small volume) at given distance

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How many of these orbitals have maximum orbital angular probability distribution at an angle of 45° to the axial direction?

dxy, dx2-y2, dyz, dxz, dz2, px, py, pz, s

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An element undergoes a reaction as shown:
x+e-x- energy released =30.87 eV
If the energy released, is used to dissociate 12 g of H2 molecules, equally into H+ and H*, where H* is an excited state, in which the electron travels a path length equal to four times it's de-Broglie wavelength. Determine the least amount (in moles) of 'x' that would be required.
Given: I.E. of H=13.6 eV/atom, Bond energy of H2=4.526 eV/molecule.

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The de Broglie wavelength of electron of He+ ion is 3.329 . If the photon emitted upon deexcitation of this He+ ion is made to hit H-atom in its ground state so as to liberate electron from it, what will be the de-Broglie's wavelength of photoelectron in  ?

Round off your answer to the nearest integer.

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de-Broglie's wavelength of an electron having kinetic energy 2.7×10-23 J is A×10-8 m. Then, what is the value of A?

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The de-Broglie wavelength of an electron travelling at x percent of the speed of light was found to be 2.42 Ao. Then, what is the value of 'x'?

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The ratio of the velocity of SO2 molecules to the velocity of O2 molecules such that they are associated with de Broglie waves of the same wavelength is

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Let the mass of a particle be 1 g and its de-Broglie wavelength 6.63×10-33 m. Then, what will be its velocity?

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If the electron is accelerated by a potential difference of 300 V, then what will be wavelength associated with the moving electron?

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Suppose the kinetic energy of a particle is doubled, de-Broglie's wavelength becomes

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Is the Bohr's model consistent with the Heisenberg's uncertainty principle?