Law of Equipartition of Energy

IMPORTANT

Law of Equipartition of Energy: Overview

This topic covers concepts, such as Energy in Gases, Molar Kinetic Energy, Molecular Kinetic Energy, Degrees of Freedom of Gas Molecule, Translational Degree of Freedom, Rotational Degree of Freedom, and Vibrational Degree of Freedom.

Important Questions on Law of Equipartition of Energy

MEDIUM
IMPORTANT

Rigid diatomic molecules of gas have how many rotational degrees of freedom?

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The total number of degrees of freedom for a non-rigid diatomic molecule is equal to:

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The number of translational degrees of freedom for a diatomic gas is 

MEDIUM
IMPORTANT

Two ideal monatomic gases A and B at 27  and 37  are mixed. The number of moles in gas A is 2 and number of moles in gas B is 3. What will be the temperature of the mixture?

EASY
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According to the kinetic theory of gases, for a diatomic molecule

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Molecule of a gas can be modelled as three sphere connected through three rigid rods as to make triangle like structure. A gas containing such molecules performs 25 J of work when it expands at constant pressure. Heat given to gas is –

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IMPORTANT

Five grams of helium having rms speed of molecules 1000 m s-1 and 24 g of oxygen having rms of 1000 m s-1 are introduced into a thermally isolated vessel. Find the rms speed of helium and oxygen individually when thermal equilibrium is attained. Neglect the heat capacity of the vessel.

EASY
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If the temperature of 3 moles of helium gas is increased by 2 K., then the change in the internal energy of helium gas is

MEDIUM
IMPORTANT

In a model of chlorine (Cl2), two Cl atoms are rotated about their centre of mass as shown. Here the two 'Cl' atoms are 2×10-10 m apart and angular speed ω=2×1012 rad s-1. If the molar mass of chlorine is 70 g mol-1, then the rotational kinetic energy of one Cl2 molecule is


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MEDIUM
IMPORTANT

Find the temperature of the mixture, if two perfectly monoatomic gases at absolute temperatures T1 and T2 number of moles in the gases are n1 and n2, respectively are mixed. Assume no loss of energy

EASY
IMPORTANT

If at a pressure of 106 dyne cm-21 gram mole of nitrogen occupies 2×104 cm3 volume, then calculate the average energy of nitrogen molecules in erg
(Given : Avogadro's number = 6×1023)