Second Law of Thermodynamics

IMPORTANT

Second Law of Thermodynamics: Overview

This topic covers concepts such as Second Law of Thermodynamics, Terms in Second Law of Thermodynamics, Efficiency in Thermodynamic Process, Engines and Cyclic Process, Entropy of Thermodynamic System, Kelvin-Planck Statement, and Clausius Statement.

Important Questions on Second Law of Thermodynamics

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In which part , air and gas(petrol) mixes in internal combustion engine?

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Given the following entropy values   (inJ K 1 mo l 1 ) at 298 K and 1 atm :   H 2 (g):130.6,C l 2 (g):223.0,HCl(g):186.7.  The entropy change   (inJ K 1 mo l 1 ) for the reaction

  H 2 (g)+C l 2 (g) 2HCl(g)is

                               

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In an experiment, 1kg of water, initially at 283K is heated to 363K via two processes. In process I, water is brought into contact with a heat reservoir at 363K. In process II, water is first brought into contact with a heat reservoir at 323K and then in contact with another reservoir at 363K. Assume that the specific heat capacity of water, C is independent of temperature. Choose the correct options from the following. (Note ln363=5.8944; ln323=5.7777; ln283=5.6454)

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An ice cube of mass 30 g at 00C is left sitting on the kitchen table where it gradually melts and reaches the kitchen temperature of 250C. The latent heat of fusion for ice is 333 J·g-1 and the specific heat of water is 4.2 J·g-1·K-1. Select the correct statement(s) about this process. (All numerical values in the answers are rounded to the closest integer.)

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Two solid blocks at temperatures T1 and T2T1<T2 are put in thermal contact for a long time inside an insulated container. Choose the correct statement(s).

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For an increase in the entropy define ____ of nature.

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Which of the following option are correct for the second law of thermodynamics?

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The process which is not reversible is called _____.

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The cause of irreversibility of a natural process is:

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Causes of irreversible process.

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The process which is not reversible is an irreversible process?

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An ideal gas heat engine operates in Carnot cycle between 227 °C and 127 °C. It absorbs 6 × 1 0 4  cal of heat at high temperature. Amount of heat converted to work is:

EASY
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Heat cannot by itself flow from a body at lower temperature to a body at higher temperature” is a statement or consequence of

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Mention the causes for irreversibility of a process.

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Graphs below show the entropy versus energy U of two systems 1 and 2 at constant volume. The initial energies of the systems are indicated by U1, i and U2, i , respectively. Graphs are drawn to the same scale. The systems are then brought into thermal contact with each other. Assume that, at all times the combined energy of the two systems remains constant. Choose the most appropriate option indicating the energies of the two systems and the total entropy after they achieve the equilibrium.

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Clausius's statement is a part of

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A refrigerator operates on:

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The wavelength associated with the electron will be

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One mole of an ideal monatomic gas undergoes the following four reversible processes:
Step 1 : It is first compressed adiabatically from volume V1 to 1 m2.
Step 2 : then expanded isothermally to volume 10 m3
Step 3 : then expanded adiabatically to volume V3
Step 4 : then compressed isothermally to volume V1. If the efficiency of the above cycle is 34 then V1 is

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Choose the incorrect relation among these