VBT for Bonding in Coordination Compounds

IMPORTANT

VBT for Bonding in Coordination Compounds: Overview

This Topic covers sub-topics such as Valence Bond Theory, Overlapping of Atomic Orbitals, Axial Overlapping, Lateral Overlapping, Directional properties of Bonds and, Formation of Sigma and Pi bonds in Ethene

Important Questions on VBT for Bonding in Coordination Compounds

MEDIUM
IMPORTANT

Number of sigma bonds in   P 4 O 10 is :

 

MEDIUM
IMPORTANT

The number of σ bonds, π bonds and lone pair of electrons in pyridine, respectively.

EASY
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Which one of the following statement is not correct for sigma-and pi-bonds formed between two carbon atoms?

HARD
IMPORTANT

The sum of number of sigma and pi bonds formed between two carbon atoms in CaC2 are:

EASY
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Number and type of bonds between two carbon atoms in CaC2 are

MEDIUM
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The number of σ and π bonds in allyl isocyanide are

EASY
IMPORTANT

The total number of sigma and pi bonds present in the given anthracene molecule are:

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EASY
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Among the following, which has zero overlapping that leads to non-bonding?

MEDIUM
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Find out the axis in which nodal plane in the π-bond of C2H4 is located. (inter-nuclear axis = Z)

MEDIUM
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In the resonating form of naphthalene molecule, how many sigma and pi bonds are present?

EASY
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Overlapping leads to the formation of σ bonding molecular orbital in:

EASY
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What is the sum of P-P bonds and P-S bonds in a molecule of P4S3?

MEDIUM
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The number of σ- and π- bonds in hexane-2, 4-dione, respectively are

HARD
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The combination of orbital that cannot produce non-bonding molecular orbital is (if an inter-nuclear axis is z-axis):

HARD
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If dxz orbital of  X and px orbital of Y from π bond along a particular molecular axis, then which bond will be formed along same molecular axis by combination of (dxy+dxy) orbitals of X and Y atom.

EASY
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Which of the following gives rise to the formation of bond?

HARD
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In which of the following back-bonding is possible

EASY
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When two atoms of hydrogen combine to form a molecule of hydrogen gas, the energy of the molecule is

MEDIUM
IMPORTANT

Which one of the following does not exhibit paramagnetism?