Electronic Effects

IMPORTANT

Electronic Effects: Overview

This Topic covers sub-topics such as Inductive Effect, Hyperconjugation, Mesomeric Effect, Electromeric Effects, Resonance Effect, Bond Order, Bond Length, Resonance Energy, Delocalised Electrons, Resonating Structures and, Conditions for Resonance

Important Questions on Electronic Effects

EASY
IMPORTANT

Which of the following compounds has maximum electron density in ring ?

MEDIUM
IMPORTANT

List the following compounds in the order of decreasing reactivity towards nucleophilic attack.

I.CH3CH2CH2-CO-CH2CH3   II.CH3CH2CHO III.CH3CH2CH(CH3)CO-C(CH3)2CHCH3

HARD
IMPORTANT

The correct stability order of the following resonating structures is:

( I ) CH2=N+-N-

( II ) CH2+-N=N-

( III ) CH2--N+N

( IV ) CH2--N=N-

 

 

MEDIUM
IMPORTANT

Number of resonance structures possible for anilinium ion are___?

HARD
IMPORTANT

The image below shows different benzene derivates that give mononitration product at ortho, meta and para positions along with the rate of nitration relative to benzene.

Question Image

Which of the following row shows atleast one INCORRECT description about the reaction?

HARD
IMPORTANT

What is the correct order of decreasing stability of following carbocations?
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HARD
IMPORTANT

Which is more stable tropylium ion or benzene ?

HARD
IMPORTANT

What is the order of - I effect.

MEDIUM
IMPORTANT

Why allylic and benzylic carbocation are more stable than tertiary carbocation?

EASY
IMPORTANT

The displacement of electrons in a multiple bond in the presence of attacking reagent is called

HARD
IMPORTANT

Which of the indicated hydrogen in the following is most acidic :

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EASY
IMPORTANT

Which of the following have negative mesomeric effect?

EASY
IMPORTANT

Which of the following have negative mesomeric effect?

EASY
IMPORTANT

What is bond order? Calculate bond order for nitrogen molecule.

EASY
IMPORTANT

Describe negative mesomeric effect.

EASY
IMPORTANT

Which of the following statements is correct?

EASY
IMPORTANT

Why are pi bonds more reactive than pi electrons are more reactive than sigma electrons?

EASY
IMPORTANT

Benzene undergoes an electrophilic addition reaction.

MEDIUM
IMPORTANT

Why benzene does not undergo electrophilic addition reaction?